For your information, the most recent version of BKChem was 0.12.0_pre3 at the time of writing.
Please, read this article to the end, because this method has some drawbacks.
As you might have noticed BKChem has built-in support for arrows. Unfortunalety, you can only create full and no half-arrowheads. That is one wedge below and one above instead of one below or above the arrow-line.
BKChem uses the “arrow” library that TK provides. Consequently, the limitation originates from TK, not BKChem itself.
However, you can create half-arrowheads with BKChem using the “vector graphics- polygon” tool.
This method can be very tedious, especially, if the half-arrowhead is very small. To fine tune the results select one corner of the wedge and move it with the cursor keys. Maybe move the wedge away from the line altogether and then rearrange the wedge with the cursor keys. You can copy-paste the arrowheads, so they look kind of identical.